REACTIONS OF (ETA-METHYLCYCLOPENTADIENYL)MANGANESE TRICARBONYL WITH PRIMARY AMINES

被引：25

作者：

SRIVASTAVA, SC

SHRIMAL, AK

SRIVASTAVA, A

机构：

[1] Department of Chemistry, University of Gorakhpur, Gorakhpur

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)83242-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(eta-CH3C5H4)Mn(CO)3 reacts with RNH2 (R = n-C4H9, sec-C4H9, n-C5H11, n-C6H13, cyclo-C6H11, n-C7H15, n-C8H17, n-C9H19 or C6H5CH2) to give corresponding sym-dialkylureas when a 1:2 molar mixture of the two reactants is irradiated with UV light for 100-250 h. The complexes (eta-CH3C5H4)Mn(CO)2(CONHR)(H) were isolated for R = n-C4H9, n-C6H13 and cyclo-C6H11.

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页码：65 / 69

页数：5

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