A CONCISE SYNTHESIS OF THE FREDERICAMYCIN-A DEF RING-SYSTEM - [4+2] CYCLOADDITION REACTIONS OF 1-AZA-1,3-BUTADIENES

被引:25
作者
BOGER, DL
ZHANG, MS
机构
[1] Department of Chemistry, Scripps Research Institute, California 92037, 10666 North Torrey Pines Road, La Jolla
关键词
D O I
10.1021/jo00040a044
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A concise four-step synthesis of the fredericamycin A DEF ring system is detailed based on the LUMO(diene)-controlled Diels-Alder reaction of N-sulfonyl-1-azadiene 3 for introduction of the pyridone F ring.
引用
收藏
页码:3974 / 3977
页数:4
相关论文
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