SYNTHESIS AND STRUCTURE OF 1,2-BIS(ORGANOTIN-BORYL)ETHENE DERIVATIVES

被引：12

作者：

FRANKHAUSER, P ^{[1
]}

PRITZKOW, H ^{[1
]}

SIEBERT, W ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,D-69120 HEIDELBERG,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1994年 / 49卷 / 02期

关键词：

CIS-1,2-BIS(DIISOPROPYLAMINO-TRIMETHYLTIN-BORYL)HEX-3-ENE; TRANS-1,2-BIS(DIISOPROPYLAMINO-TRIMETHYLTHIN-BORYL)ETHENE;

D O I：

10.1515/znb-1994-0216

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trimethyltinlithium reacts with z-1,2-bis(diisopropylamino-chloro-boryl)ethene derivatives 4a (R = Et) and 4b (R = H) to give the cis-1,2-bis(diisopropylamino-trimethyltin-boryl)- hexene-3 (2a) and, surprisingly, the trans-1,2-bis(diisopropylamino-trimethyltin-boryl)- ethene (5b) respectively. The constitution of 2a and 5b is derived from spectroscopic data, and confirmed by X-ray structure analyses. The formation of the trans-product 5b probably occurs via a radial intermediate.

引用

页码：250 / 254

页数：5

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