SYNTHETIC APPLICATIONS OF 2-CHLORO-1,3-DITHIANE .2. REACTIONS WITH CARBON NUCLEOPHILES

被引：50

作者：

KRUSE, CG ^{[1
]}

WIJSMAN, A ^{[1
]}

VANDERGEN, A ^{[1
]}

机构：

[1] UNIV LEIDEN,DEPT ORGAN CHEM,NL-2300 RA LEIDEN,NETHERLANDS

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 11期

关键词：

D O I：

10.1021/jo01325a022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of 2-chloro-1, 3-dithiane (2) with several carbon nucleophiles are described. Introduction not only of primary alkyl but also of aryl, vinyl, and secondary alkyl groups at C-2 of 1, 3-dithiane can be effected by reaction with the corresponding Grignard reagents. In addition, the syntheses of 2-(1, 3-dithianyl) derivatives of malonic esters and of electron-rich aromatic compounds are described. © 1979, American Chemical Society. All rights reserved.

引用

页码：1847 / 1851

页数：5

共 30 条

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