THE EFFECT OF LIGAND VARIATION ON THE RATE OF CYCLODODECANE OXIDATION UNDER MODIFIED GO AGG-2 CONDITIONS

被引：45

作者：

ABOUTJAUDET, E

BARTON, DHR

CSUHAI, E

OZBALIK, N

机构：

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(00)88846-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effect of various ligands on the GoAggII oxidation of cyclododecane to cyclododecanone has been investigated. The addition of picolinic acid and a number of its congeners increases the rate of oxidation up to fiftyfold. On the other hand, the addition of pyridine-2-phosphonic acid stops oxidation completely. © 1990.

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页码：1657 / 1660

页数：4

相关论文

共 14 条

[1] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .10. A COMPARATIVE-STUDY OF CHEMICAL AND ELECTROCHEMICAL PROCESSES (GIF AND GIF-ORSAY SYSTEMS) IN PYRIDINE, IN ACETONE AND IN PYRIDINE-CO-SOLVENT MIXTURES [J].

BALAVOINE, G ;

BARTON, DHR ;

BOIVIN, J ;

GREF, A ;

LECOUPANEC, P ;

OZBALIK, N ;

PESTANA, JAX ;

RIVIERE, H .

TETRAHEDRON, 1988, 44 (04) :1091-1106

[2]

BALAVOINE G, IN PRESS TETRAHEDRON

[3] THE REACTION OF SUPEROXIDE RADICALS WITH METAL PICOLINATE COMPLEXES [J].

BANNISTER, WH ;

BANNISTER, JV ;

SEARLE, AJF ;

THORNALLEY, PJ .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1983, 78 (03) :139-142

[4]

Barton D. H. R., 1983, J CHEM SOC CHEM COMM, V41

[5]

BARTON DHR, 1986, NEW J CHEM, V10, P387

[6] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .14. FURTHER-STUDIES ON THE MECHANISM OF GIF-TYPE SYSTEMS [J].

BARTON, DHR ;

HALLEY, F ;

OZBALIK, N ;

SCHMITT, M ;

YOUNG, E ;

BALAVOINE, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (18) :7144-7149

[7]

BARTON DHR, 1989, NEW J CHEM, V13, P177

[8] PREPARATION OF AMINOPHENYLPHOSPHONATES, NITROPHENYLPHOSPHONATES, PYRIDYLPHOSPHONATES, AND QUINOLYLPHOSPHONATES UNDER PHOTOSTIMULATION OR METALLIC ASSISTANCE - ACCESS TO CORRESPONDENT AMINOPHOSPHONIC ACIDS [J].

BULOT, JJ ;

ABOUJAOUDE, EE ;

COLLIGNON, N ;

SAVIGNAC, P .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1984, 21 (02) :197-204

[9] MODEL COMPOUNDS FOR THE OXIDIZED UTEROFERRIN PHOSPHATE COMPLEX - SYNTHESES, CRYSTAL-STRUCTURES, AND MAGNETIC-PROPERTIES OF MU-PHOSPHATO-BRIDGED, MU-ARSENATO-BRIDGED, AND MU-CHROMATO-BRIDGED BINUCLEAR IRON(III) COMPLEXES [J].

DRUEKE, S ;

WIEGHARDT, K ;

NUBER, B ;

WEISS, J ;

FLEISCHHAUER, HP ;

GEHRING, S ;

HAASE, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (23) :8622-8631

[10] SULFONIC ACIDS DERIVED FROM PYRIDINE AND 2,6-LUTIDINE AND CORRESPONDING N-OXIDES [J].

EVANS, RF ;

BROWN, HC .

JOURNAL OF ORGANIC CHEMISTRY, 1962, 27 (04) :1329-&