SYNTHETIC STUDIES OF MARINE ALKALOIDS HAPALINDOLES .2. LITHIUM ALUMINUM-HYDRIDE REDUCTION OF THE ELECTRON-RICH CARBON-CARBON DOUBLE-BOND CONJUGATED WITH THE INDOLE NUCLEUS

被引：22

作者：

MURATAKE, H ^{[1
]}

NATSUME, M ^{[1
]}

机构：

[1] RES FDN ITSUU LAB,2-28-10 TAMAGAWA,SETAGAYA KU,TOKYO 158,JAPAN

来源：

TETRAHEDRON | 1990年 / 46卷 / 18期

关键词：

D O I：

10.1016/S0040-4020(01)96006-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

- A reaction mechanism is proposed for an unusual, reduction of the electron-rich C-C double bond with lithium aluminum hydride in the indole derivatives such as 3. Liberation of an aluminum hydride anion from 1-indolylaluminum intermediates, i.e., 27 may play an important role for the inversion of the polarity at the 15 position. © 1990.

引用

页码：6343 / 6350

页数：8