ACTIVATION OF SMALL MOLECULES BY TRANSITION-METALS - REACTION OF CS2 WITH ETA-5-C5H5MO(CO)3R(R=ME,ET)

被引：3

作者：

COVILLE, NJ

ALBERS, MO

机构：

[1] Department of Chemistry, University of the Witwatersrand, Johannesburg

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 172卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81862-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of CS2 with η5-C5H5Mo(CO)3R (R = Me, Et) yields the η2-CS2 complexes η5-C5H5Mo(CO)2(η2-CS2)(COR) which can reversibly lose CS2 in refluxing benzene to reform the starting material. Reaction of η5-C5H5Mo(CO)2(η2-CS2)(COMe) with PPh3 yields η5-C5H5Mo(CO)2(η2-CS2)(PPh3)(COMe). © 1976.

引用

收藏

页码：C1 / C3

页数：3

相关论文

共 8 条

[1] ACTIVATION OF CARBON-DISULFIDE BY TRANSITION-METAL COMPLEXES [J].

BUTLER, IS ;

FENSTER, AE .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 66 (02) :161-194

[2]

COTTON FA, 1972, ADV INORG CHEM, P696

[3] THIOCARBONYL, H2-DITHIOMETHYL ESTER, AND DITHIOCARBENE COMPLEXES DERIVED FROM CARBON-DISULFIDE COMPLEXES OF RUTHENIUM AND OSMIUM [J].

GRUNDY, KR ;

HARRIS, RO ;

ROPER, WR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 90 (02) :C34-C36

[4] NEW PREPARATIVE METHOD FOR SYNTHESIS OF DITHIOCARBOXYLATE COMPLEXES OF RHENIUM [J].

LINDNER, E ;

GRIMMER, R ;

WEBER, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 23 (01) :209-&

[5] ALKYL AND ARYL DERIVATIVES OF PI-CYCLOPENTADIENYL COMPOUNDS OF CHROMIUM, MOLYBDENUM, TUNGSTEN, AND IRON [J].

PIPER, TS ;

WILKINSON, G .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1956, 3 (02) :104-124

[6] SYNTHESIS AND CLEAVAGE REACTIONS OF THIOCARBONYL-BRIDGED CP2FE2(CO)3CS, AND PREPARATION OF CARBENE COMPLEXES CPFE(CO)C(N2C2H6)SNPH3 AND ]CPFE(CO)2C(OME)2]PF6 [J].

QUICK, MH ;

ANGELICI, RJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 160 (01) :231-239

[7]

Vol'pin M.E., 1973, PURE APPL CHEM, V33, P567

[8] THIOCARBONYL AND RELATED COMPLEXES OF TRANSITION-METALS [J].

YANEFF, PV .

COORDINATION CHEMISTRY REVIEWS, 1977, 23 (02) :183-220