FREE-RADICAL COUPLING OF ALKYL AND ARYL HALIDES WITH ELECTRON-DEFICIENT ALKENES MEDIATED BY CHROMIUM(II) COMPLEXES .2.

被引：21

作者：

TASHTOUSH, HI

SUSTMANN, R

机构：

[1] UNIV ESSEN GESAMTHSCH,INST ORGAN CHEM,POSTFACH 103764,W-4300 ESSEN 1,GERMANY

[2] YARMOUK UNIV,DEPT CHEM,IRBID,JORDAN

来源：

CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 07期

关键词：

BOND FORMATION; C-C; CHROMIUM(II) COMPLEXES; RADICALS;

D O I：

10.1002/cber.19931260736

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Free radicals generated from organic halides and (ethylenediamine)chromium(II) complexes in DMF are trapped by electron-deficient olefins. The coupling reactions of alkyl halides, described in Part I[1], are extended and, in addition, aryl halides are shown to be efficient radical precursors to yield coupling products in good yield.

引用

页码：1759 / 1761

页数：3

共 27 条

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