REACTION OF DECABORANE WITH THE PHOSPHAALKYNE PCTBU

被引：11

作者：

MEYER, F ^{[1
]}

PAETZOLD, P ^{[1
]}

ENGLERT, U ^{[1
]}

机构：

[1] TH AACHEN,INST ANORGAN CHEM,D-52056 AACHEN,GERMANY

来源：

CHEMISCHE BERICHTE | 1994年 / 127卷 / 01期

关键词：

DECABORANE; 1-PHOSPHABUTIN, 3,3-DIMETHYL-; BIS(DECABORANYL)METHANE;

D O I：

10.1002/cber.19941270115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The borane B10H12(SMe(2))(2) (1) reacts with the phosphaalkyne P drop CtBu to form the product [B10H11(SMe(2))][C(tBu)-PH](B10H12) (2), in which two B-10 units are Linked by a HP-CtBu bridge. The B-10 unit B is simply bound to the bridge C atom, whereas the B-10 unit A is bound to both bridging atoms, P and C, by atom B6 and, moreover, to the P atom by atom B5. The solvate complex 2 CH2 . Cl-2 crystallizes in the space group $($) over bar$$ P1.

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页码：93 / 95

页数：3

相关论文

共 19 条

[1]

APPEL R, 1990, MULTIPLE BONDS LOW C, pS157

[2] ACYLIDENPHOSPHINES AND ALKYLIDENEPHOSPHINES .15. 2,2-DIMETHYLPROPYLIDYNEPHOSPHINE, A STABLE COMPOUND WITH A PHOSPHORUS ATOM OF COORDINATION NUMBER-1 [J].

BECKER, G ;

GRESSER, G ;

UHL, W .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1981, 36 (01) :16-19

[3] DISTRIBUTION OF BOND ELECTRONS IN DECABORANE MOLECULE (B1OH14) [J].

BRILL, R ;

DIETRICH, H ;

DIERKS, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (OCT15) :2003-+

[4] CRYSTAL AND MOLECULAR-STRUCTURE OF 5,6-MU-DIPHENYLPHOSPHINO-DECABORANE(14) [J].

FRIEDMAN, LB ;

PERRY, SL .

INORGANIC CHEMISTRY, 1973, 12 (02) :288-293

[5] NOVEL SYNTHESIS OF TRIBOROHYDRIDE ANION, -B3H8 [J].

GRAYBILL, BM ;

RUFF, JK ;

HAWTHORNE, MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (12) :2669-&

[6] A NEW SERIES OF ORGANOBORANES .1. CARBORANES FROM REACTION OF DECABORANE WITH ACETYLENIC COMPOUNDS [J].

HEYING, TL ;

AGER, JW ;

CLARK, SL ;

MANGOLD, DJ ;

GOLDSTEIN, HL ;

HILLMAN, M ;

POLAK, RJ ;

SZYMANSKI, JW .

INORGANIC CHEMISTRY, 1963, 2 (06) :1089-+

[7] KINETICS AND MECHANISM OF CARBORANE FORMATION [J].

HILL, WE ;

JOHNSON, FA ;

NOVAK, RW .

INORGANIC CHEMISTRY, 1975, 14 (06) :1244-1249

[8] CHEMISTRY OF BORANES-II .1. DECABORANE DERIVATIVES BASED ON THE B10H12 STRUCTURAL UNIT [J].

KNOTH, WH ;

MUETTERTIES, EL .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 20 (1-2) :66-72

[9] 1-ALKYL-1-AZA-CLOSO-DODECABORANE - A NOVEL ACCESS TO THE ICOSAHEDRAL NB11 SKELETON [J].

MEYER, F ;

MULLER, J ;

SCHMIDT, MU ;

PAETZOLD, P .

INORGANIC CHEMISTRY, 1993, 32 (23) :5053-5057

[10] CRYSTAL AND MOLECULAR-STRUCTURE OF 9-CYCLOHEXYL-5(7)-(DIMETHYL SULFIDE)-NIDO-DECABORANE(11), B10H11C6H11S(CH3)2 [J].

MIZUSAWA, E ;

RUDNICK, SE ;

ERIKS, K .

INORGANIC CHEMISTRY, 1980, 19 (05) :1188-1191