COMPUTER EVALUATION OF ENTROPY TITRATION DATA . CALORIMETRIC DETERMINATION OF LOG BETAI DELTAHI DEGREES AND DELTASI DEGREES VALUES FOR SILVE(I)- AND COPPER(2)-PYRIDINE SYSTEMS

被引：72

作者：

IZATT, RM

EATOUGH, D

SNOW, RL

CHRISTEN.JJ

机构：

[1] Departments of Chemistry and Chemical Engineering, Brigham Young University, Provo

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1968年 / 72卷 / 04期

关键词：

D O I：

10.1021/j100850a023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Log βi, ΔHi°, and ΔSi° values have been determined in aqueous solution at 25° using a calorimetric titration procedure for the stepwise formation of AgPy2+ and CuPy42+ (Py = pyridine) from their constituent ions. The results agree well with previously determined values where available and demonstrate that titration calorimetry can be used to determine log K, ΔH°, and ΔS° values for metal-ligand systems involving simultaneous equilibria. Four iterative methods of data analysis are compared and discussed.

引用

页码：1208 / &

共 23 条

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