SYNTHESIS AND CHARACTERIZATION OF FUNCTIONAL POLYMERS CONTAINING AZOXYCARBAMATE AND PEROXYCARBAMATE GROUPS

被引：3

作者：

BAYSAL, BM ^{[1
]}

机构：

[1] BOGAZICI UNIV,POLYMER RES CTR,ISTANBUL 80815,TURKEY

来源：

BRITISH POLYMER JOURNAL | 1990年 / 23卷 / 1-2期

关键词：

D O I：

10.1002/pi.4980230105

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this review, the synthesis and characterization of various dimeric and polymeric peroxycarbamates and azocarbamates are described in detail. These functional polymers are synthesized by stepwise capping reactions of hydroxyl terminated polyethers, polyesters or poly(butadiene) first with diisocyanates, and then with hydroperoxides or various azo compounds containing functional groups. Statistics of chain extension reactions are discussed. Kinetic parameters of thermal decomposition are reported. These functional polymers are useful for preparing block copolymers containing soft and glassy segments.

引用

页码：19 / 22

页数：4

共 15 条

[1] SYNTHESIS AND CHARACTERIZATION OF SOME NEW POLYMERIC PEROXYCARBAMATES [J].

BAYSAL, BM ;

TOBOLSKY, AV ;

SHORT, WT .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1972, 10 (03) :909-&

[2]

BAYSAL BM, 1974, J POLYM SCI POLYM S, V46, P237

[3]

BAYSAL BM, 1972, METU J PURE APPL SCI, V5, P193

[4] PREPARATION OF BLOCK COPOLYMERS BY USE OF PEROXIDE-TERMINATED PREPOLYMER [J].

ERDY, NZ ;

FERRARO, CF ;

TOBOLSKY, AV .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1970, 8 (03) :763-&

[5] Molecular size distribution in linear condensation polymers [J].

Flory, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1936, 58 :1877-1885

[6]

ORHAN E, 1977, POLYMER, V10, P285

[7] KINETICS OF URETHANE CLEAVAGE IN CROSSLINKED POLYURETHANES [J].

SINGH, A ;

WEISSBEI.L .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1966, 4 (10PA) :2551-&

[8]

Sperling LH., 1981, INTERPENETRATING POL

[9]

Tobolsky A. V., 1964, J APPL POLYM SCI, V8, P307

[10]

UYANIK N, 1990, J APPL POLYM SCI

← 1 2 →