HYDROGEN-BOND NETWORKS IN SUPERCOOLED LIQUID WATER AND AMORPHOUS VITREOUS ICES

被引:25
作者
DORE, JC
机构
[1] Physics Laboratory, University of Kent, Canterbury
关键词
D O I
10.1016/0022-2860(90)80141-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structural characteristics of hydrogen bonding in water and ices can be studied by neutron diffraction. This short review concerns recent work on temperature variation and isotopic substitution measurements for the normal and supercooled liquid phase with additional data for solid phases prepared by vapour-deposition and hyperquenched processes. The combined data suggest that the behaviour of low-temperature water can be understood in terms of a systematic evolution of local hydrogen-bonded configurations towards the continuous random hydrogen-bonded network of the amorphous/vitreous ices. © 1990.
引用
收藏
页码:221 / 232
页数:12
相关论文
共 18 条
  • [1] ANGELL A, 1982, WATER COMPREHENSIVE, V7
  • [2] A STRUCTURAL STUDY OF DEEPLY SUPERCOOLED WATER
    BELLISSENTFUNEL, MC
    TEIXEIRA, J
    BOSIO, L
    DORE, JC
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1989, 1 (39) : 7123 - 7129
  • [3] SPATIAL CORRELATIONS IN DEEPLY SUPERCOOLED WATER
    BELLISSENTFUNEL, MC
    TEIXEIRA, J
    BOSIO, L
    DORE, J
    CHIEUX, P
    [J]. EUROPHYSICS LETTERS, 1986, 2 (03): : 241 - 245
  • [4] THE STRUCTURAL CHARACTERISTICS OF AMORPHOUS D2O ICE BY NEUTRON-DIFFRACTION
    CHOWDHURY, MR
    DORE, JC
    WENZEL, JT
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1982, 53 (03) : 247 - 265
  • [5] DORE JC, 1985, WATER SCI REV, V1, P3
  • [6] DORE JC, 1984, MOL LIQUIDS DYNAMICS, P383
  • [7] STRUCTURAL REARRANGEMENTS IN LOW-TEMPERATURE HEAVY-WATER
    EGELSTAFF, PA
    POLO, JA
    ROOT, JH
    HAHN, LJ
    CHEN, SH
    [J]. PHYSICAL REVIEW LETTERS, 1981, 47 (24) : 1733 - 1736
  • [8] GARAWI M, UNPUB
  • [9] GEIGER A, 1984, J PHYS PANS C, P13
  • [10] NEUTRON-DIFFRACTION STUDIES OF WATER .3. STRUCTURAL-CHANGE AS A FUNCTION OF TEMPERATURE
    GIBSON, IP
    DORE, JC
    [J]. MOLECULAR PHYSICS, 1983, 48 (05) : 1019 - 1030