ONE-POT SYNTHESIS OF AMINES BY AMINOMETHYLATION OF ALKENES CATALYZED BY DINUCLEAR RHODIUM COMPLEXES UNDER MILD CONDITIONS

被引：27

作者：

BAIG, T ^{[1
]}

KALCK, P ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM,CHIM PROCEDES LAB,118 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 18期

关键词：

D O I：

10.1039/c39920001373

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [Rh2(mu-S-Bu(t))2(CO)2(PPh3)2] With a slight excess of PPh3 catalyses the aminomethylation reaction of terminal alkenes under low pressures of carbon monoxide and hydrogen.

引用

页码：1373 / 1374

页数：2

共 9 条

[1] Cornils B, 1980, NEW SYNTHESIS CARBON
[2] IQBAL AFM, 1971, HELV CHIM ACTA, V45, P1440
[3] NOVEL ACTIVE DIRHODIUM COMPLEXES FOR THE LOW-PRESSURE HYDROFORMYLATION REACTION - UNEXPECTED INHIBITING EFFECT OF HIGH PARTIAL PRESSURES OF HYDROGEN
KALCK, P
PERES, Y
QUEAU, R
MOLINIER, J
ESCAFFRE, P
DEOLIVEIRA, EL
PEYRILLE, B
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 426 (01) : C16 - C20
[4] CATALYSIS OF THE AMINOMETHYLATION REACTION - ENHANCED CATALYTIC ACTIVITY WITH MIXED-METAL CATALYSTS - APPLICATIONS OF THE WATER-GAS SHIFT REACTION .5.
LAINE, RM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (16) : 3370 - 3372
[5] MACENTIRE EE, 1986, Patent No. 240193
[6] MARCH J, 1985, ADV ORGANIC CHEM
[7] CARBONYLATIONS WITH CO/H2O AND CO/H2 CATALYZED BY CO2(CO)8-1,2-BIS(DIPHENYLPHOSPHINO)ETHANE COMPLEXES
MURATA, K
MATSUDA, A
MASUDA, T
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1984, 23 (01): : 121 - 132
[8] NEUERE ENTWICKLUNGEN AUF DEM GEBIETE DER CHEMIE DES ACETYLENS UND KOHLENOXYDS
REPPE, W
[J]. EXPERIENTIA, 1949, 5 (03): : 93 - 110
[9] Reppe W., 1953, LIEBIGS ANN CHEM, V583, P148

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