AZIRIDINATION OF ELECTRON-RICH ACYCLIC ALLYLIC ALCOHOLS USING 3-ACETOXYAMINOQUINAZOLINONES

被引：19

作者：

ATKINSON, RS

FAWCETT, J

RUSSELL, DR

WILLIAMS, PJ

机构：

[1] Department of Chemistry, The University, Leicester

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 18期

关键词：

D O I：

10.1016/0040-4039(95)00453-J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The products from aziridination of the phenyl-substituted allylic alcohols 6 and 7 with 3-acetoxyaminoquinazolinones 1 and 15 have been compared with those from aziridination of the methyl ester analogues 2, and 3: the differences in diastereoselectivities using these electron-rich and electron-deficient alkenes are ascribed to the intervention of transition states 8 and 4 respectively.

引用

页码：3241 / 3244

页数：4

共 6 条

[1] AZIRIDINATION BY OXIDATIVE ADDITION OF N-AMINOQUINAZOLONES TO ALKENES - EVIDENCE FOR NON-INVOLVEMENT OF N-NITRENES
ATKINSON, RS
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[2] STEREOSELECTIVITY IN ADDITION OF N-NITRENES TO OLEFINS
ATKINSON, RS
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ATKINSON, RS
FAWCETT, J
RUSSELL, DR
WILLIAMS, PJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (18) : 2031 - 2032
[4] AZIRIDINATION OF CYCLOHEX-2-ENOLS AND 3-SUBSTITUTED CYCLOHEXENES - COMPARISON WITH EPOXIDATION
ATKINSON, RS
KELLY, BJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (08): : 1515 - 1519
[5] ATKINSON RS, 1985, J CHEM SOC P1, V341, P325
[6] CHELATE CONTROL IN THE RHODIUM-CATALYZED HOMOGENEOUS HYDROGENATION OF CHIRAL ALLYLIC AND HOMOALLYLIC ALCOHOLS
BROWN, JM
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (06) : 348 - 350

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