RADICAL IONS .28. TRIS(TRIMETHYLSILYLMETHYL)AMINIUM, .+N(CH2SI(CH3)3)3 - STABLE FLUXIONAL AMINIUM RADICAL CATION

被引：35

作者：

BOCK, H ^{[1
]}

KAIM, W ^{[1
]}

KIRA, M ^{[1
]}

OSAWA, H ^{[1
]}

SAKURAI, H ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 03期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/S0022-328X(00)81693-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first ionization potentials of 11 silylmethyl-substituted amines R3-nN(CH2Si(CH3)3)n as determined photoelectron spectroscopy range from 9.07 eV to 7.66 eV. The most easily ionized molecule, N(CH2Si(CH3)3)3, can also be oxidized with AlCl3 in H2CCl2 solution to its aminium radical cation. The ESR spectra recorded between 180 K and 310 K display a strong temperature dependence due to rotations around the >NCH2bonds. © 1979.

引用

页码：295 / 304

页数：10

共 56 条

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