CLAISEN ORTHOESTER REARRANGEMENT REACTION WITH SECONDARY AND TERTIARY ALLYLIC ALCOHOLS - SYNTHESIS OF 1,2 SECOCHRYSANTHEMATES AND THEIR STRUCTURAL ANALOGS

被引:8
作者
KELKAR, SV
ARBALE, AA
JOSHI, GS
KULKARNI, GH
机构
[1] National Chemical Laboratory, Pune
关键词
D O I
10.1080/00397919008052329
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A simple route is described for the synthesis of 1,2 Seco-chrysanthemic acid and their structural analogues, employing Claisen orthoester rearrangement reaction in the key-step of synthesis. These acids have been prepared with a view to evaluating some of the esters prepared from them for possible insecticidal and other biological properties. Copyright © 1990 by Taylor & Francis Group. All rights reserved.
引用
收藏
页码:839 / 847
页数:9
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