A NOVEL OXIDATIVE AZIDATION OF AROMATIC-COMPOUNDS WITH HYPERVALENT IODINE REAGENT, PHENYLIODINE(III) BIS(TRIFLUOROACETATE) (PIFA) AND TRIMETHYLSILYL AZIDE

被引：142

作者：

KITA, Y

TOHMA, H

INAGAKI, M

HATANAKA, K

YAKURA, T

机构：

[1] Faculty of Pharmaceutical Sciences, Osaka University 1-6, Suita, Osaka, 565, Yamada-oka

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)92160-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and useful method for the azidation of aromatic compounds by the reaction of hypervalent iodine reagent, phenyliodine(III) bis(trifluoroacetate) (PIFA) in 1,1,1,3,3,3-hexafluoro-2-propanol followed by treatment of trimethylsilyl azide (TMSA) was developed. The possible mechanism is also discussed.

引用

页码：4321 / 4324

页数：4

共 20 条

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