REACTION OF LITHIUM SILYLAMIDES WITH CARBON-MONOXIDE LEADING TO CARBAMOYLSILANES

被引：30

作者：

ORITA, A ^{[1
]}

OHE, K ^{[1
]}

MURAI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 04期

关键词：

D O I：

10.1021/om00016a068

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Carbamoylsilanes, a hitherto little known class of compounds, are obtained by the reaction of lithium silylamides with carbon monoxide followed by quenching with methyl iodide. The reaction involves initial formation of a carbamoyllithium species and subsequent rearrangement of the silyl group to give a lithium (silylcarbonyl)amide.

引用

页码：1533 / 1536

页数：4

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