PREPARATION OF TRANSITION-METAL COMPLEXES OF CHIRAL DERIVATIVES OF ACETOACETIC ACID - TETRAALKYLAMMONIUM TETRACHLOROMETALLATES AS AN ORGANIC SOURCE OF METALS

被引：12

作者：

GALVEZ, N ^{[1
]}

MORENOMANAS, M ^{[1
]}

PADROS, I ^{[1
]}

SEBASTIAN, RM ^{[1
]}

SERRA, N ^{[1
]}

VALLRIBERA, A ^{[1
]}

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT CHEM,E-08193 BARCELONA,SPAIN

来源：

POLYHEDRON | 1995年 / 14卷 / 10期

关键词：

D O I：

10.1016/0277-5387(95)00066-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(benzyltrimethylammonium) tetrachlorocuprate, tetrachlorocobaltate and hexachlorodiferrate react in organic solvents with alkaline salts of CH3COCH2CO-X(c) [X(c)-H = (d)-menthol, (4S)-4-benzyl-2-oxazolidinone and (2R)-bornane-10,2-sultam] to give homochiral beta-dicarbonyl metal complexes.

引用

页码：1397 / 1399

页数：3

共 11 条

[1] THE CHIRAL POOL AS A SOURCE OF ENANTIOSELECTIVE CATALYSTS AND AUXILIARIES [J].

BLASER, HU .

CHEMICAL REVIEWS, 1992, 92 (05) :935-952

[2] ACETOACETYLATION WITH "2,2,6-TRIMETHYL-4H-1,3-DIOXIN-4-ONE - A CONVENIENT ALTERNATIVE TO DIKETENE [J].

CLEMENS, RJ ;

HYATT, JA .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (14) :2431-2435

[3] SYNTHESIS AND CATALYTIC REACTIONS OF CHIRAL N-(DIAZOACETYL)OXAZOLIDONES [J].

DOYLE, MP ;

DOROW, RL ;

TERPSTRA, JW ;

RODENHOUSE, RA .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (10) :1663-1666

[4] STUDIES OF PLANAR-TETRAHEDRAL CONFIGURATIONAL EQUILIBRIUM IN SOLUTIONS OF BIS(BETA-KETOAMINO)COBALT(2) COMPLEXES [J].

EVERETT, GW ;

HOLM, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (11) :2442-&

[5] SYNTHESIS AND PROTON RESONANCE STUDY OF SOLUTION EQUILIBRIA OF BIS(BETA-KETOAMINO)NICKEL(2) COMPLEXES [J].

EVERETT, GW ;

HOLM, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (10) :2117-&

[6] PREPARATION OF COBALT(II) COMPLEXES OF BETA-KETO-ESTERS [J].

HARRIS, PG ;

HOUGHTON, RP ;

TAYLOR, PL .

POLYHEDRON, 1992, 11 (22) :2957-2960

[7] A RADICAL-ORGANOMETALLIC GLYCINE SYNTHON - PREPARATION OF HOMOCHIRAL HETEROCYCLIC ALPHA-AMINO-ACIDS [J].

LLORIS, ME ;

MORENOMANAS, M .

TETRAHEDRON LETTERS, 1993, 34 (44) :7119-7122

[8] DEVELOPMENT OF METHODS FOR THE SYNTHESIS OF CHIRAL, HIGHLY FUNCTIONALIZED 2-AMINO-4-ARYL-4H-PYRANS [J].

MARCO, JL ;

MARTIN, N ;

MARTINEZGRAU, A ;

SEOANE, C ;

ALBERT, A ;

CANO, FH .

TETRAHEDRON, 1994, 50 (11) :3509-3528

[9] PREPARATION OF CYCLOHEXANONES AND CYCLOPENTANONES OF HIGH OPTICAL PURITY [J].

TABER, DF ;

SALEH, SA ;

KORSMEYER, RW .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (23) :4699-4702

[10] STEREOCHEMICAL AND REGIOCHEMICAL STUDIES ON THE ALKYLATION OF PENTANE-2,4-DIONE THROUGH ITS CO(II) COMPLEX [J].

VALLRIBERA, A ;

SERRA, N ;

MARQUET, J ;

MORENOMANAS, M .

TETRAHEDRON, 1993, 49 (29) :6451-6462

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