A BENEFICIAL EFFECT OF ORTHO-SUBSTITUENTS IN THE ARYLATION OF (BENZENE)TRICARBONYLMANGANESE(1+) HEXAFLUOROPHOSPHATE(1-)

被引：8

作者：

ASTLEY, DK ^{[1
]}

ASTLEY, ST ^{[1
]}

机构：

[1] EGE UNIV,FAC SCI,DEPT CHEM,IZMIR 35100,TURKEY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期

关键词：

MANGANESE; CARBONYL; ARENE COMPLEXES; ORTHOMETALLATION; METAL CARBONYL CATIONS;

D O I：

10.1016/0022-328X(94)05085-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

ortho-Substituted aryllithium and aryl Grignard reagents react with (benzene)manganesetricarbonyl cation (1) to give good yields of the expected ring adducts. The presence of the ortho substituent(s) appears to be necessary for the satisfactory outcome of the reaction with aryllithiums. This reactivity opens up the possibility of preparing novel heterocyclic structures via the initial reaction of 1 with functionalised metallated arenes.

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页码：253 / 255

页数：3

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