SUBSTITUTED TETRALIN FORMATION FROM ORTHO-PALLADATED SCHIFF-BASES AND 2 EQUIVALENTS OF METHYL ACRYLATE

被引：34

作者：

CHAO, CH

HART, DW

BAU, R

HECK, RF

机构：

[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90007

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19711

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 179卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0022-328X(00)91747-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

ortho-Palladated complexes of N-phenylbenzaldimine and N-phenyl-p-anisaldiimine reacted at 150°C with methyl acrylate by undergoing two successive methyl acrylate insertions followed by a cyclization to form tetralin derivatives in ca. 10% yield. The structure of the product from the N-phenylbenzaldimine complex was established by X-ray crystallography. The reactions appear to involve vinylic palladation as an intermediate step. © 1979.

引用

页码：301 / 309

页数：9

共 10 条

[1]

BRESLOW R, 1970, ORG SYN, V50, P102

[2] STUDIES OF METAL-NITROGEN MULTIPLE BONDS .I. CRYSTAL AND MOLECULAR STRUCTURE OF NITRIDODICHLOROTRIS(DIETHYLPHENYLPHOSPHINE)RHENIUM(V) RENCL2[P(C2H5)2C6H5]3 [J].