SYNTHESIS OF 4-THIO-D-MANNOSE

被引：11

作者：

SHAH, RH

BOSE, JL

BAHL, OP

机构：

[1] Division of Cell and Molecular Biology, Department of Biological Sciences, State University of New York at Buffalo, Buffalo

来源：

CARBOHYDRATE RESEARCH | 1979年 / 77卷 / DEC期

关键词：

D O I：

10.1016/S0008-6215(00)83797-0

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

1,6-Anhydro-4-S-benzoyl-4-thio-β-D-mannopyranose, obtained by treatment of 1,6:3,4-dianhydro-β-D-talopyranose with pyridinium thiolbenzoate in N,N-di-methylformamide, was converted into its 2,3-di-O-acetyl derivative, which was acetolyzed to give 1,2,3,6-tetra-O-acetyl-4-S-benzoyl-4-thio-D-mannopyranose. Deacylation of the last-named compound with sodium methoxide in methanol gave syrupy 4-thio-D-mannose, which was characterized as 1,2,3,5,6-penta-O-acetyl-4-thio-α- and -β-D-mannofuranose. © 1979.

引用

页码：107 / 115

页数：9

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