SYNTHESIS OF 1,1-DI-TERT-BUTYLSILIRANE, THE 1ST SILIRANE WITH NO SUBSTITUENTS ON THE RING CARBONS

被引：64

作者：

BOUDJOUK, P

BLACK, E

KUMARATHASAN, R

机构：

[1] Department of Chemistry, North Dakota State University, Fargo

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 07期

关键词：

D O I：

10.1021/om00053a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,1-Di-tert-butylsilirane was prepared from thermolysis of 7,7-di-tert-butyl-7-silabicyclo[4.1.0]heptane in the presence of ethylene. NMR data as well as thermal and photochemical reactions suggest this silirane is fundamentally different from its more substituted analogues.

引用

页码：2095 / 2096

页数：2

共 12 条

[1] STEREOCHEMISTRY OF THE ADDITION OF DIARYLSILYLENES TO CIS-2-BUTENES AND TRANS-2-BUTENES
ANDO, W
FUJITA, M
YOSHIDA, H
SEKIGUCHI, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (10) : 3310 - 3311
[2] Blinka T.A., 1984, ADV ORGANOMET CHE, P193, DOI 10.1016/S0065-3055(08)60611-5
[3] THEORETICAL-STUDIES OF 3-MEMBERED RING COMPOUNDS Y2H4X (Y=C, SI, X = CH2, NH, O, SIH2, PH, S)
BOATZ, JA
GORDON, MS
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (08) : 3025 - 3029
[4] CONVENIENT ROUTES TO DI-TERT-BUTYLSILANEDIYL - CHEMICAL, THERMAL AND PHOTOCHEMICAL GENERATION
BOUDJOUK, P
SAMARAWEERA, U
SOORIYAKUMARAN, R
CHRUSCIEL, J
ANDERSON, KR
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (10) : 1355 - 1356
[5] BOUDJOUK P, 1988, ULTRASOUND CHEM PHYS
[6] BOUDJOUK P, 1991, 24 ORG S EL PAS
[7] SYNTHESES OF PALLADIUM(0) AND PLATINUM(0) OLEFIN COMPLEXES - MOLECULAR-STRUCTURES OF [PT(C2F4)(C2H4)2] AND TRIS(BICYCLO[2.2.1]HEPTENE) PLATINUM
GREEN, M
HOWARD, JAK
SPENCER, JL
STONE, GA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (11) : 449 - 451
[8] SYNTHESIS OF ETHYLENE, CYCLO-OCTA-1,5-DIENE, BICYCLO[2.2.1]HEPTENE, AND TRANS-CYCLO-OCTENE COMPLEXES OF PALLADIUM(0) AND PLATINUM(0) - CRYSTAL AND MOLECULAR-STRUCTURE OF "TRIS(BICYCLO[2.2.1]HEPTENE)PLATINUM
GREEN, M
HOWARD, JAK
SPENCER, JL
STONE, FGA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (03): : 271 - 277
[9] Mann B.E., 1974, ADV ORGANOMET CHEM, V12, P135
[10] HEXAMETHYLSILIRANE .1. PREPARATION, CHARACTERIZATION AND THERMAL-DECOMPOSITION
SEYFERTH, D
ANNARELLI, DC
VICK, SC
DUNCAN, DP
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 201 (01) : 179 - 195

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