TEMPORARY ANIONS OF THE FLUOROETHYLENES

被引：92

作者：

CHIU, NS ^{[1
]}

BURROW, PD ^{[1
]}

JORDAN, KD ^{[1
]}

机构：

[1] UNIV PITTSBURGH, DEPT CHEM, PITTSBURGH, PA 15260 USA

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80082-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron transmission spectroscopy is employed to measure the gas phase electron affinities of the fluoroethylenes. Fluorination is found to destabilize the π* anions with respect to that of ethylene. The role of bond length changes as well as inductive and resonance effects is examined. © 1979.

引用

页码：121 / 126

页数：6

共 27 条

[1] RESONANT SCATTERING OF ELECTRONS BY MOLECULES
BARDSLEY, JN
MANDL, F
[J]. REPORTS ON PROGRESS IN PHYSICS, 1968, 31 : 471 - &
[2] RELATIVE STABILITY OF 1,2-DIFLUOROETHYLENES
BINKLEY, JS
POPLE, JA
[J]. CHEMICAL PHYSICS LETTERS, 1977, 45 (02) : 197 - 200
[3] OVERLAPPING SPHERES X-ALPHA CALCULATIONS OF THE ELECTRON-AFFINITIES AND IONIZATION-POTENTIALS OF ETHYLENE, PARABENZOQUINONE AND THEIR PERFLUORO DERIVATIVES
BLOOR, JE
PAYSEN, RA
SHERROD, RE
[J]. CHEMICAL PHYSICS LETTERS, 1979, 60 (03) : 476 - 482
[4] Virtual negative ion spectra of hydrocarbons
Boness, M. J. W.
Larkin, I. W.
Hasted, J. B.
Moore, L.
[J]. CHEMICAL PHYSICS LETTERS, 1967, 1 (07) : 292 - 294
[5] N(1AG), T(3B1U), AND V(1B1U) STATES OF VERTICAL ETHYLENE
BROOKS, BR
SCHAEFER, HF
[J]. JOURNAL OF CHEMICAL PHYSICS, 1978, 68 (11) : 4839 - 4847
[6] PERFLUORO EFFECT IN PHOTOELECTRON SPECTROSCOPY .1. NON-AROMATIC MOLECULES
BRUNDLE, CR
BASCH, H
ROBIN, MB
KEUBLER, NA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (05) : 1451 - &
[7] MRD-CI STUDY OF THE VERTICAL 1(PI, PI-STAR) V-N TRANSITION OF ETHYLENE USING AN AO-BASIS WITH OPTIMIZED RYDBERG ND-PI-SPECIES AND 2 SEPARATE CARBON-D POLARIZATION FUNCTIONS
BUENKER, RJ
SHIH, SK
PEYERIMHOFF, SD
[J]. CHEMICAL PHYSICS, 1979, 36 (01) : 97 - 111
[8] ELECTRON AFFINITIES OF ETHYLENE AND 1,3-BUTADIENE
BURROW, PD
JORDAN, KD
[J]. CHEMICAL PHYSICS LETTERS, 1975, 36 (05) : 594 - 598
[9] GAS-PHASE ELECTRON-DIFFRACTION STUDY OF 6 FLUOROETHYLENES
CARLOS, JL
KARL, RR
BAUER, SH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1974, 70 : 177 - 187
[10] ELECTRON-IMPACT SPECTROSCOPY OF FLUOROETHYLENES
COGGIOLA, MJ
FLICKER, WM
MOSHER, OA
KUPPERMANN, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (07) : 2655 - 2667

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