MATRIX-ISOLATION PHOTOLYSIS OF SO2, O3 AND H2O - EVIDENCE FOR THE H2O-SO3 COMPLEX

被引：50

作者：

SCHRIVER, L ^{[1
]}

CARRERE, D ^{[1
]}

SCHRIVER, A ^{[1
]}

JAEGER, K ^{[1
]}

机构：

[1] ALFRED WEGENER INST POLAR & MARINE RES,W-2850 BREMERHAVEN,GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 181卷 / 06期

关键词：

D O I：

10.1016/0009-2614(91)80303-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mechanism of H2SO4 formation via the reaction steps, [GRAPHICS] has been investigated at low temperature in an argon matrix. Photooxidation of SO2 mainly occurs through the SO2:O3 pairs. Photolysis of a SO2-H2O-O3 mixture did not lead to the H2SO4 molecule. The 1:1 H2O:SO3 complex was identified in nitrogen matrix. Observed isotope shifts in the IR absorption of the water submolecule suggest that the complexation proceeds through charge transfer with an O...S interaction.

引用

页码：505 / 511

页数：7

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