ON THE THEORY OF ADSORPTION-KINETICS OF IONIC SURFACTANTS AT FLUID INTERFACES .3. GENERALIZATION OF THE MODEL

被引：28

作者：

DUKHIN, SS

MILLER, R

机构：

[1] CENT INST ORGAN CHEM,RUDOWER CHAUSSE 5,W-1199 BERLIN,GERMANY

[2] ACAD SCI UKSSR,INST COLLOID & WATER CHEM,KIEV,UKRAINE,USSR

来源：

COLLOID AND POLYMER SCIENCE | 1991年 / 269卷 / 09期

关键词：

ADSORPTION KINETICS; THEORY; IONIC SURFACTANTS;

D O I：

10.1007/BF00657309

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It was shown that, in the case of adsorbing ions, the Boltzmann equation cannot be applied in its classical form, but has to be modified by considering the flux of adsorbing ions. From the comparison with the adsorption of nonionic surfactants a ratio results which is the measure of deceleration of adsorption kinetics due to the electric double layer r = K (y(s))/delta(t). At high r-values the electrostatic deceleration controls the adsorption kinetics process.

引用

页码：923 / 928

页数：6

共 13 条

[1] EQUILIBRIUM AND DYNAMICS OF ADSORPTION OF SURFACTANTS AT FLUID-FLUID INTERFACES [J].