A VO3+ COMPLEX INCORPORATING AROMATIC CARBOXYLATE BINDING - SYNTHESIS, STRUCTURE AND METAL REDOX

被引：13

作者：

CHAKRAVARTY, J ^{[1
]}

DUTTA, S ^{[1
]}

CHAKRAVORTY, A ^{[1
]}

机构：

[1] INDIAN ASSOC CULTIVAT SCI,DEPT INORGAN CHEM,CALCUTTA 700032,W BENGAL,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期

关键词：

D O I：

10.1039/c39930001091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title complex [VOL1L2] derived from the tridentate 2-hydroxy-2'-carboxy-5-methylazobenzene (H2L1) and the bidentate quinolin-8-ol (HL2) the V-O(carboxylate) and V-N(azo) distances are respectively 1.892(4) and 2.098(5) angstrom; frozen solution (77 K) EPR parameters of electrogenerated [VOL1L2]- lie close to those of reduced bromoperoxidase (low pH).

引用

页码：1091 / 1092

页数：2

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