CONTINUOUS EMULSION POLYMERIZATION - MODELING OSCILLATIONS IN VINYL-ACETATE POLYMERIZATION

被引：69

作者：

KIPARISSIDES, C

MACGREGOR, JF

HAMIELEC, AE

机构：

[1] Department of Chemical Engineering, Mcmaster University, Hamilton, Ontario

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1979年 / 23卷 / 02期

关键词：

D O I：

10.1002/app.1979.070230210

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A theoretical investigation of the emulsion polymerization of vinyl acetate in a continuous stirred tank reactor operating under conditions of sustained oscillations is reported here. Models of two levels of sophistication are developed: a comprehensive model that solves for the age distribution function of polymer particles and a simplified model that assumes discrete nucleation periods. The latter model should find use in adaptive control of latex reactors. These models adequately simulate experimental data after Greene et al.2 for the emulsion polymerization of vinyl acetate under conditions of sustained oscillations. Copyright © 1979 John Wiley & Sons, Inc.

引用

页码：401 / 418

页数：18

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