REACTIONS OF CARBON-MONOXIDE AND PHENOLS PROMOTED BY PALLADIUM COMPLEXES

被引:48
作者
HALLGREN, JE
MATTHEWS, RO
机构
[1] General Electric Company Corporate Research and Development Schenectady
关键词
D O I
10.1016/S0022-328X(00)82305-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of phenols with carbon monoxide at atmospheric pressure and room temperature in the presence of palladium cholrode and tertiary amine produces diaryl carbonates and aryl salicylates. Only diaryl cabonates are produced when palladium carbonyl cholride is substituted for palladium chloride. Reaction pathways are proposed. © 1979.
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页码:135 / 142
页数:8
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