RELATIVE RATE CONSTANTS OF O(1D2)-OLEFIN REACTIONS

被引：17

作者：

KAJIMOTO, O

FUENO, T

机构：

[1] Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 64卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80218-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The relative rate constants for the reactions of O(1D2) with several olefins were determined at room temperature by measuring the amount of N2 produced in the competitive reactions between N2O and olefin toward O(1D2). The derived rate constants (relative to N2O) are as follows: ethylene 1.8, propylene 5.0, trans-2-butene 4.9, cis-butene 7.2, 2-methyl- propene 3.7, and 2-methyl-2-butene 8.9. © 1979.

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页码：445 / 447

页数：3

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