COMPLEXES OF GROUP(IV) METAL-HALIDES WITH PYRAZOLONES

被引：9

作者：

ZAIDI, SAA

KHAN, TA

NEELAM, NS

机构：

[1] Department of Chemistry, Aligarh Muslim University

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1979年 / 9卷 / 03期

关键词：

D O I：

10.1080/00945717908057460

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and characterization of Ge(lV), Sn(lV), Ti(lV) and Zr(lV) halide complexes of antipyrine and 4-aroino-antlpyrine have been described. The low frequency IR spectra indicate a trans-octahedral geometry involving unidentate or bidentate ligands, however, a cis -octahedral structure is proposed for the GeCl complex of 4-aminoantipyrine. A polymeric structure is proposed for the lsl complexes of 4-aminoantipyrine involving ligand bridging through the carbonyl oxygen and the amino nitrogen. © 1979, Taylor & Francis Group, LLC. All rights reserved.

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页码：243 / 249

页数：7

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