BECKMANN FRAGMENTATION AND SUCCESSIVE CARBON-CARBON BOND FORMATION OF ALPHA-ALKOXYCYCLOALKANONE OXIMES CATALYZED BY TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE

被引：15

作者：

FUJIOKA, H

MIYAZAKI, M

YAMANAKA, T

YAMAMOTO, H

KITA, Y

机构：

[1] Faculty of Pharmaceutical Sciences, Osaka University, Suita, Osaka, 565

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(00)98002-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Title reaction occurred in the presence of silicon-containing carbon nucleophiles and various types of functionalized ω-nitrile compounds (3) were obtained from the oximes (1) in one-pot operation. © 1990.

引用

页码：5951 / 5954

页数：4

共 9 条

[1]

GAWLEY RE, 1986, ORG REACTIONS, V35, P1

[2] MECHANISMS AND STEREOCHEMISTRY OF HETEROLYTIC FRAGMENTATION [J].

GROB, CA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (08) :535-&

[3] HETEROLYTIC FRAGMENTATION . A CLASS OF ORGANIC REACTIONS [J].

GROB, CA ;

SCHIESS, PW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1967, 6 (01) :1-&

[4]

Heldt W. Z., 1960, ORG REACTIONS, V11, P1

[5]

MARCH J, 1985, ADV ORG CHEM, P931

[6]

MCCARTY CG, 1970, CHEM CARBON NITROGEN, P416

[7] EVIDENCE FOR AND SYNTHETIC UTILITY OF BECKMANN FISSION INTERMEDIATE OF 2-METHOXYCYCLOHEXANONE OXIME [J].

OHNO, M ;

TERASAWA, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (23) :5683-&

[8]

OHNO M, 1968, KAGAKU NO RYOIKI, V22, P30

[9]

Tennant G., 1979, COMPREHENSIVE ORGANI, V1, P528

← 1 →