CHIROPTICAL PROPERTIES OF STEROID 1,3-DIAXIAL DIOLS IN THE PRESENCE OF [MO2(OAC)4]

被引：26

作者：

FRELEK, J

SNATZKE, G

SZCZEPEK, WJ

机构：

[1] RUHR UNIV BOCHUM,CHAIR STRUCT CHEM,W-4630 BOCHUM 1,GERMANY

[2] POLISH ACAD SCI,DEPT CHEM,PL-02093 WARSAW,POLAND

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1993年 / 345卷 / 11期

关键词：

D O I：

10.1007/BF00325835

中图分类号：

O65 [分析化学];

学科分类号：

070302 [分析化学]; 081704 [应用化学];

摘要：

Bidentate complexes of dimolybdenum tetra-acetate with 1,3-diaxial diols show Cotton effects around 490-540 nm (CD band I), 400-440 nm (II), 350-380 nm (III), 320 nm (IV) and 280 nm (V). The sign of the Cotton effect Il can be predicted by a proposed sector rule. It seems that from the Cotton effects for cyclic 1,3-diols the absolute configurations or conformations can be obtained.

引用

页码：683 / 687

页数：5

共 19 条

[1]

TRUE COURSE OF SOLVOLYSIS OF 3-BETA-TOSYLOXY-5-BETA-HYDROXYCHOLESTAN-6-ONE, OR SN2 INVERSION RULE UPHELD [J].