FACTORS AFFECTING INFRA-RED SPECTRA OF PLANAR ANIONS WITH D3H SYMMETRY .4. VIBRATIONAL SPECTRA OF SOME COMPLEX CARBONATES IN REGION 4000-400 CM-1

被引：37

作者：

GOLDSMITH, JA

ROSS, SD

机构：

[1] Department of Chemistry, Chelsea College of Science and Technology, Chelsea, London, England

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1968年 / A 24卷 / 08期

关键词：

D O I：

10.1016/0584-8539(68)80120-5

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The infra-red spectra of four unidentate and five bidentate cobalt (III) carbonato complexes have been studied as Nujol and hexachlorobutadiene mulls and as alkali halide disks. Splitting of the degenerate vibrations is greater in bidentate than in unidentate complexes, but the intensity of the forbidden transition is not. The results of treating the complexed system independently of, and including, the metal atom are compared. © 1968.

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页码：993 / +

页数：1

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