ON A NEW FAMILY OF TITANIUM OXIDES AND NATURE OF SLIGHTLY-REDUCED RUTILE

被引:109
作者
BURSILL, LA
HYDE, BG
TERASAKI, O
WATANABE, D
机构
[1] Chemistry Department, University of Western Australia, Nedlands, WA
[2] Physics Department, Tohoku University, Sendai
来源
PHILOSOPHICAL MAGAZINE | 1969年 / 20卷 / 164期
关键词
D O I
10.1080/14786436908228706
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
An electron microscope investigation of slightly reduced rutile (TiOx x= 1·986, 1·94) suggests the existence of a new family of ordered phases, probably TinO2n-1 (n=15,…∼36), derived from rutile by crystallographic shear on planes parallel to (132). Still smaller ce:degrees of reduction (x= 1·995) introduce disordered shear planes parallel to (132) and (101). Some comments on the mechanism of reduction are also included. © 1969 Taylor & Francis Group, LLC.
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页码:347 / &
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