USE OF BIOGENETIC KEY COMPOUNDS FOR THE BIOMIMETIC SYNTHESIS OF NATURAL-PRODUCTS - (S)-ELENOLIDE FROM SECOLOGANIN

被引：6

作者：

TIETZE, LF

UZAR, HC

机构：

[1] Organisch-Chemisches Institut Der Universität, Göttingen, D-3400

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 07期

关键词：

D O I：

10.1002/anie.197905391

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mimicry of nature has considerable advantages in the synthesis of alkaloids and similar substances; just a few reaction steps generally lead to enantiomerically pure products. The three‐step synthesis of S‐elenolide 2 from secologanin 1 is an example. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：539 / 540

页数：2

共 8 条

[1] BEYERMAN HC, 1961, B SOC CHIM FR, P1812
[2] SYNTHESIS AND STEREOCHEMICAL ASSIGNMENT OF CIS-AND TRANS-2-METHYL-2-PENTENOIC ACID AND CORRESPONDING ESTERS,ALDEHYDES,AND ALCOHOLS
CHAN, KC
JEWELL, RA
NUTTING, WH
RAPOPORT, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (09) : 3382 - &
[3] CORDELL GA, 1974, LLOYDIA, V37, P219
[4] COREY EJ, 1975, TETRAHEDRON LETT, P2647
[5] BIOSYNTHESIS OF SECOIRIDOID GLUCOSIDES
INOUYE, H
UEDA, S
TAKEDA, Y
[J]. HETEROCYCLES, 1976, 4 (03) : 527 - 565
[6] Panizzi L., 1960, GAZZ CHIM ITAL, V90, P1449
[7] TIETZE LF, 1976, TETRAHEDRON LETT, P2535
[8] TIETZE LF, 1976, CHEM BER, V109, P3640

← 1 →