FLUORESCENCE YIELD NEAR EDGE SPECTROSCOPY (FYNES) OF BENZENE ADSORBED IN NA-Y ZEOLITE

被引：11

作者：

FISCHER, DA

GLAND, JL

DAVIS, SM

机构：

[1] EXXON RES & DEV LABS,BATON ROUGE,LA 70821

[2] BROOKHAVEN NATL LAB,EXXON PRT,UPTON,NY 11973

来源：

CATALYSIS LETTERS | 1990年 / 6卷 / 01期

关键词：

Benzene; Fluorescence Yield Near Edge Spectroscopy (FYNES); Na-Y zeolite;

D O I：

10.1007/BF00764058

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Benzene adsorbed in sodium-Y zeolite has been investigated using Fluorescence Yield Near Edge Spectroscopy (FYNES). These studies demonstrate that FYNES measurements are feasible as a direct probe of the local electronic structure of hydrocarbons adsorbed in and on insulating, microporous practical catalysts. The distribution of π energy levels for adsorbed benzene was not significantly altered as compared to the condensed phase. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.

引用

页码：99 / 102

页数：4

共 17 条

[1]

BARTHOMEUF D, 1973, J CHEM SOC FARAD T 1, V69, P2158, DOI 10.1039/f19736902158

[2]

BULOW M, 1983, JCS F1, V79, P183

[3]

BULOW M, 1983, JCS F1, V79, P54

[4] SITE-SPECIFIC ISOTHERMS FOR BENZENE ADSORPTION IN NA-Y ZEOLITE [J].