ABSORPTION-SPECTRUM OF THE SOLVATED ELECTRON IN AMMONIA AND AMINES

被引：15

作者：

ABRAMCZYK, H

KROH, J

机构：

[1] Institute of Applied Radiation Chemistry, Technical University, 93-950 Łódź

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 15期

关键词：

D O I：

10.1021/j100168a009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absorption spectra of solvated electrons in ammonia, methylamine, and trimethylamine are calculated in terms of the theory presented in our previous paper1 and compared with the experimental data. The theory reproduces very well the experimental absorption spectra, their bandwidths, and the band shapes with the characteristic asymmetric tail on the high-frequency side. The role of the H bond in stabilization and spectroscopic properties of the solvated electron in amines are discussed.

引用

页码：5749 / 5753

页数：5

共 86 条

[1]

ABRAMCZYK H, IN PRESS J PHYS CHEM

[2]

[Anonymous], 1960, HYDROGEN BOND

[3] EXCESS ELECTRONS IN CONDENSED MEDIA - THEORY OF OPTICAL-ABSORPTION SPECTRUM IN MOLECULAR SOLUTIONS [J].