STUDIES ON POLYTHIOCUPRATES(I) [CU(SX)]- .3. CRYSTAL-STRUCTURE OF [H3N-C2H4-NH3][CU(S5)]2.4H2O

被引：14

作者：

KIEL, G ^{[1
]}

GATTOW, G ^{[1
]}

DINGELDEIN, T ^{[1
]}

机构：

[1] UNIV MAINZ,INST ANORGAN CHEM & ANALYT CHEM,JOHANN JOACHIM BECHER WEG 24,W-6500 MAINZ,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 596卷 / 05期

关键词：

POLYTHIOCUPRATES(I); ETHYLENEDIAMMONIUM BIS(PENTATHIOCUPRATE(I)) TETRAHYDRATE; SYNTHESIS; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19915960116

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound crystallizes with Z = 2 in the monoclinic space group P2(1)/c (Nr. 14) with cell dimensions a = 8.820(1) angstrom, b = 15.532(3) angstrom and beta = 96.92(4)-degrees. For 2368 independent reflections the structure was refined to R = 0.070 and R(W) = 0.045. The structure contains endless [Cu(S5)]n(n-) anion-chains parallel-to c and is stabilized by hydrogen bonds N-H...S, N-H...O, O-H...S, and O-H...O. Each copper atom is tetrahedrally coordinated by four sulfur atoms from three different (S5)2- chains. There are CuS4 and Cu2S2 five-ring systems, which are linked together by common edges forming the one-dimensional chains.

引用

页码：111 / 119

页数：9

共 22 条

[1] THE PREPARATION AND CRYSTAL-STRUCTURE OF AN ANIONIC SILVER PENTASULFIDE CHAIN IN INFINITY[AG(S5)-](ME4N+) [J].

BANDA, RMH ;

CRAIG, DC ;

DANCE, IG ;

SCUDDER, ML .

POLYHEDRON, 1989, 8 (19) :2379-2383

[2] ALKYLAMMONIUM POLYSULFIDE .2. THE CRYSTAL-STRUCTURE OF ETHYLENEDIAMMONIUM HEXASULFIDE [J].

BOTTCHER, P ;

BUCHKREMERHERMANNS, H ;

BARON, J .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1984, 39 (04) :416-420

[3]

BOTTCHER P, 1987, Z NATURFORSCH B, V42, P267

[4] THE CRYSTAL-STRUCTURE OF NH4CUS4 [J].

BURSCHKA, C .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1980, 35 (12) :1511-1513

[5]

DRAGANJAC M, 1985, ANGEW CHEM, V97, P745

[6] ON CHALCOGENOLATES .176. REACTION OF ACETAMIDINE WITH CARBON-DISULFIDE .5. CRYSTAL AND MOLECULAR-STRUCTURE OF N-ACETIMIDOYL DITHIOCARBAMIC ACID [J].

EUL, W ;

KIEL, G ;

GATTOW, G .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1987, 544 (01) :149-158

[7] ON CHALCOGENOLATES .197. STUDIES ON POLYTHIOCUPRATES(I) [CU(SX)]- .1. PROPERTIES AND REACTIONS OF AMMONIUM TETRATHIOCUPRATE(I) [J].

GATTOW, G ;

DINGELDEIN, T .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1990, 590 (11) :127-136

[8] ON CHALCOGENOLATES .198. STUDIES ON POLYTHIOCUPRATES(I) [CU(SX)] .2. HYDRAZINIUM AND ETHYLENEDIAMMONIUM POLYTHIOCUPRATES(I) [J].

GATTOW, G ;

DINGELDEIN, T .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1991, 592 (01) :84-92

[9] SYNTHESIS AND STRUCTURE OF [PH4P]2[CU6(S4)3S5], A POLYCYCLIC HEXANUCLEAR COPPER(I) CLUSTER WITH COMPLETE SULFUR COORDINATION [J].

HENKEL, G ;

BETZ, P ;

KREBS, B .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (05) :314-315

[10] POLYCHALCOGENIDE SYNTHESIS IN MOLTEN-SALTS - NOVEL ONE-DIMENSIONAL COMPOUNDS IN THE K/CU/S SYSTEM CONTAINING EXCLUSIVELY S42- LIGANDS [J].

KANATZIDIS, MG ;

PARK, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (10) :3767-3769

← 1 2 3 →