SYNTHESIS OF POLYPYRIDYL COMPLEXES OF RUTHENIUM(II) CONTAINING 3 DIFFERENT BIDENTATE LIGANDS

被引：101

作者：

STROUSE, GF

ANDERSON, PA

SCHOONOVER, JR

MEYER, TJ

KEENE, FR

机构：

[1] UNIV N CAROLINA, VENABLE & KENAN LABS, DEPT CHEM, CHAPEL HILL, NC 27599 USA

[2] JAMES COOK UNIV N QUEENSLAND, DEPT CHEM & BIOCHEM, TOWNSVILLE, QLD 4811, AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 14期

关键词：

D O I：

10.1021/ic00040a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A general synthetic method has been developed for the synthesis of heteroleptic tris(polypyridyl) complexes of ruthenium(II), [Ru(pp)(pp')(pp")]2+. This method opens new avenues for the preparation of molecular assemblies and for the systematic variation of excited-state properties. For example, the results of a study on the ground- and excited-state properties of a series of these complexes reveal a strategy for the preparation of black chromophores which will absorb light strongly throughout the visible region of the spectrum.

引用

页码：3004 / 3006

页数：3

共 68 条

[1]

ALLAN GH, 1984, J AM CHEM SOC, V106, P2613

[2] INORGANIC PHOTOPHYSICS IN SOLUTION .3. TEMPERATURE ACTIVATION OF DECAY PROCESSES IN THE LUMINESCENCE OF TRIS(2,2'-BIPYRIDINE)OSMIUM(II) AND "TRIS(1,10-PHENANTHROLINE)OSMIUM(II) IONS [J].