APPLICATION OF CHEMOMETRIC METHODS IN RAMAN-SPECTROSCOPIC STUDIES OF MOLTEN-SALT SYSTEM CONTAINING MGCL2-KCL - EXPERIMENTAL-EVIDENCE FOR EXISTENCE OF MG2CL73- DIMER AND ITS RAMAN-SPECTRUM

被引：11

作者：

DAI, S

BEGUN, GM

YOUNG, JP

MAMANTOV, G

机构：

[1] OAK RIDGE NATL LAB,DIV ANALYT CHEM,OAK RIDGE,TN 37831

[2] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1995年 / 26卷 / 10期

关键词：

D O I：

10.1002/jrs.1250261002

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Investigation of the Raman spectra of the molten MgCl2-KCl system by the use of factor analysis indicates that the melt is a two-component system involving equilibrium between MgCl42- and Mg2Cl73-. The pure Raman spectra corresponding to these two species are recovered from the broad features via a self-modeling method.

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页码：929 / 932

页数：4

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