KINETICS OF THERMAL-DECOMPOSITION OF THE SOLID-STATE .2. DELIMITING THE HOMOGENEOUS-REACTION MODEL

被引：34

作者：

GARN, PD

机构：

[1] The University of Akron, Akron

来源：

THERMOCHIMICA ACTA | 1990年 / 160卷 / 02期

关键词：

D O I：

10.1016/0040-6031(90)80254-V

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Present evidence shows that many thermal processes can be described by the generalized rate equation. -dx/dt = Z exp(E*/RT)f(x) but many others cannot. Still others may be adequately describable by a modified equation. A small set of tests will enable the experimenter to determine whether or not the equation applies. These include change of sample size, change of sample geometry, and extended time of reaction. © 1990.

引用

页码：135 / 145

页数：11

共 50 条

[1]

ACHAR BN, 1966, P INT CLAY C JER, P67

[2] EXPERIMENTAL-STUDY OF NON-ISOTHERMAL KINETIC-EQUATIONS AND COMPENSATION EFFECT [J].