STRUCTURE OF DIBENZYL SULFOXIDE ADDUCT OF N-TRIPHENYLSTANNYL-1,2-BENZISOTHIAZOL-3(2H)-ONE 1,1-DIOXIDE

被引：10

作者：

NG, SW ^{[1
]}

WEI, C ^{[1
]}

DAS, VGK ^{[1
]}

机构：

[1] UNIV MALAYA,DEPT CHEM,KUALA LUMPUR 59100,MALAYSIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192003299

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[1,2-Benzisothiazol-3(2H)-one 1,1-dioxide-N](dibenzyl sulfoxide-O)triphenyltin(IV), [Sn(C14-H14OS)(C7H4NO3S)(C6H5)3], [(C6H5)3SnNC(O) C6H4SO2.OS(CH2C6H5)2], M(r)=762.50, monoclinic, P2(1), a = 10.9026 (7) b = 19.614 (1), c = 16.821 1 (9) angstrom, beta = 94.512 (5)-degrees, V = 358 5.8 (8) angstrom3, Z = 4, D(x) = 1.412 g CM-3 , lambda(Mo Kalpha) = 0.71073 angstrom, mu = 8.64 cm-1, F(000) = 1552, T = 298 K, R = 0.038 for 4729 reflections [I greater-than-or-equal-to 3sigma(1)]. The Sn atoms in the two independent molecules exhibit a tranS-C3SnNO trigonal bipyramidal geometry. In molecule A, the Sn-N bond [2.237 (8) angstrom] is short and the Sn-0 bond [2.413 (7) angstrom] long; in molecule B, the Sn-N bond [2.253 (9) angstrom] is longer whereas the Sn-O bond [2.376 (7) angstrom] is shorter.

引用

页码：2211 / 2213

页数：3

共 5 条

[1]

FAIR CK, 1990, MOIEN STRUCTURE DETE

[2]

NG SW, 1989, J ORGANOMET CHEM, V376, P277

[3]

NG SW, 1989, J ORGANOMET CHEM, V379, P247

[4] TRIPHENYLTIN DERIVATIVES OF ISOTHIAZOL-3(2H)-ONE 1,1-DIOXIDES - SYNTHESIS, MOSSBAUER-SPECTRA, SOME FUNGITOXICITY DATA, AND CRYSTAL-STRUCTURE OF TRIPHENYLSTANNYL 1,2-BENZISOTHIAZOL-3(2H)-ONE 1,1-DIOXIDE.N,N-DIMETHYLFORMAMIDE [J].

NG, SW ;

KUTHUBUTHEEN, AJ ;

ARIFIN, ZD ;

CHEN, W ;

DAS, VGK ;

SCHULZE, B ;

MOLLOY, KC ;

YIP, WH ;

MAK, TCW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 403 (1-2) :101-109

[5]

NG SW, 1989, J ORGANOMET CHEM, V378, P339

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