SPATIAL AND TEMPORAL DECAY OF LOCALIZED-ELECTRONS IN SOLIDS - ONE-DIMENSIONAL MODEL

被引：25

作者：

VEKHTER, BG ^{[1
]}

RATNER, MA ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,MAT RES CTR,EVANSTON,IL 60208

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 101卷 / 11期

关键词：

D O I：

10.1063/1.467936

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The competing effects of transfer integral (bandwidth) and local vibronic coupling on space- and time-dependent decay of initially localized electrons in anharmonic chains are investigated. The dynamics of electronic localization, caused by electron-vibrational interaction, and the energy redistribution between the electron and lattice is examined and shown to be changed drastically by the appearance of vibrations, localized by vibronic coupling. We consider effects of dynamical disorder, caused by thermal fluctuations, and find that increase in temperature produces diffuse (incoherent) transfer with the conductivity dropping off with temperature increase, as expected in a metal. © 1994 American Institute of Physics.

引用

页码：9710 / 9715

页数：6

共 33 条

[1] DYNAMIC SOLVENT EFFECTS ON ELECTRON-TRANSFER RATES IN THE INVERTED REGIME - ULTRAFAST STUDIES ON THE BETAINES [J].