DICYCLOPENTADIENYLTITANIUM-DIPHENOXIDES

被引：67

作者：

ANDRA, K

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 11卷 / 03期

关键词：

D O I：

10.1016/0022-328X(68)80085-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(C5H5)2TiCl2 reacts in benzene with phenol or substituted phenols in presence of NaNH2 as a strong base by formation of dicyclopentadienyltitanium diphenoxide (C5H5)2Ti(OR)2. Pyrocatechol and 2,2′-dihydroxybiphenyl react to form cyclic compounds with five- and seven-membered rings, respectively whereas 1,8-dihydroxynaphthalene does not give the analogous six-membered ring. © 1968.

引用

页码：567 / &

共 9 条

[1] ANDRA K, 1967, Z CHEM, V7, P318
[2] DUB M, 1966, ORGANOMETALLIC CO ED, V1
[3] ERDMANN H, 1888, JUSTUS LIEBIGS ANN C, V247, P344
[4] BIS(CYCLOPENTADIENYL)TITANIUM(4) COMPOUNDS WITH SULFUR-CONTAINING GROUPS
GIDDINGS, SA
[J]. INORGANIC CHEMISTRY, 1967, 6 (04) : 849 - &
[5] GIDDINGS SA, 1962, CA 9881, V57
[6] GIDDINGS SA, Patent No. 3030395
[7] BIS-PI-CYCLOPENTADIENYL-TITAN-MERCAPTIDE
KOPF, H
SCHMIDT, M
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1965, 340 (3-4): : 139 - &
[8] BIS-CYCLOPENTADIENYL DERIVATIVES OF SOME TRANSITION ELEMENTS
WILKINSON, G
PAUSON, PL
BIRMINGHAM, JM
COTTON, FA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (04) : 1011 - 1012
[9] [No title captured]

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