CATION-EXCHANGE SEPARATION OF METALS IN DIMETHYL SULPHOXIDE-AQUEOUS HYDROCHLORIC ACID MEDIA

被引：19

作者：

BIRZE, I

MARPLE, LW

DIEHL, H

机构：

[1] Department of Chemistry, Iowa State University, Ames, IA

来源：

TALANTA | 1968年 / 15卷 / 12期

关键词：

D O I：

10.1016/0039-9140(68)80204-8

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The behaviour of bismuth, cadmium, copper, lead, silver, tin and zinc on a cation-exchange resin in a solvent system consisting of dimethyl sulphoxide, hydrochloric acid and water was studied. The distribution coefficients of these metal ions between liquid and resin were determined as functions of the concentration of dimethyl sulphoxide and of hydrochloric acid. On the basis of the distribution coefficients found, predictions were made as to the possibilities of separating these metals from mixtures. Such separations were confirmed experimentally for bismuth from lead, bismuth from copper, zinc from lead, lead from cadmium, silver from copper, silver from lead, lead from cadmium from zinc, bismuth from lead from zinc, and bismuth from zinc from copper. © 1968.

引用

页码：1441 / &