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DIRECT-CURRENT ELECTROCHEMILUMINESCENCE OF RU(BPY)32+
被引:9
作者:
IGARASHI, R
NOSAKA, Y
MIYAMA, H
KANEKO, M
YOKOYAMA, M
机构:
[1] INST PHYS & CHEM RES,WAKO 35101,JAPAN
[2] NIPPON SEIKI CO LTD,NAGAOKA 940,JAPAN
关键词:
Cathodes - Chemiluminescence - Display Devices - Electrodes - Luminescence;
D O I:
10.1149/1.2095474
中图分类号:
O646 [电化学、电解、磁化学];
学科分类号:
081704 ;
摘要:
Direct current (dc) electrochemiluminescence (ECL) of tris(2,2′-bipyridine)ruthenium(II) [Ru(bpy)32+RB was observed in acetonitrile solution by using an Al-sheet working electrode at negative potential. The dc ECL was originated from the excited state of Ru(bpy)32+. Characteristics of the luminescence were as follows: (i) the luminescence was continued for several hours, (ii) response time of the luminescence was faster than that of alternating current ECL, and (iii) the luminescence was observed all over the sheet electrode.
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页码:2987 / 2990
页数:4
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