OXO TRANSFER-REACTIONS OF MO(VI) COMPLEXES TO PHOSPHINES AND PHOSPHITES

被引：30

作者：

SPEIER, G

机构：

[1] Veszprém Unlversity of Chemical Engineering, Department of Organic Chemistry

来源：

INORGANICA CHIMICA ACTA | 1979年 / 32卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)91651-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxygenation reactions of aldehydes, tertiary phosphines and phosphites catalyzed by the cis-dioxomolybdenum(VI)-ethyl-L-cysteinate complex were studied. The reaction with aldehydes seems to have a radical character and that with phosphines and phorphites involves an oxo transfer from molybdenu m to trivalent phosphorus. Some attempts were made to find a correlation between reactivity and structure of the substrates. © 1979.

引用

页码：139 / 141

页数：3

共 18 条

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