OXO TRANSFER-REACTIONS OF MO(VI) COMPLEXES TO PHOSPHINES AND PHOSPHITES

被引:30
作者
SPEIER, G
机构
[1] Veszprém Unlversity of Chemical Engineering, Department of Organic Chemistry
关键词
D O I
10.1016/S0020-1693(00)91651-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The oxygenation reactions of aldehydes, tertiary phosphines and phosphites catalyzed by the cis-dioxomolybdenum(VI)-ethyl-L-cysteinate complex were studied. The reaction with aldehydes seems to have a radical character and that with phosphines and phorphites involves an oxo transfer from molybdenu m to trivalent phosphorus. Some attempts were made to find a correlation between reactivity and structure of the substrates. © 1979.
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页码:139 / 141
页数:3
相关论文
共 18 条
  • [1] BARRAL R, 1972, TETRAHEDRON LETT, P1693
  • [2] BOWDEN FL, 1975, TECHNIQUES TOPICS BI, P207
  • [3] Bray R. C., 1972, STRUCT BOND, V11, P107
  • [4] SYNTHESIS OF MO(IV) AND MO(V) COMPLEXES USING OXO ABSTRACTION BY PHOSPHINES - MECHANISTIC IMPLICATIONS
    CHEN, GJJ
    MCDONALD, JW
    NEWTON, WE
    [J]. INORGANIC CHEMISTRY, 1976, 15 (11) : 2612 - 2615
  • [5] KINETICS AND MECHANISM OF OXYGEN-TRANSFER REACTION BETWEEN BIS-(DIETHYLDITHIOCARBAMATO)DIOXOMOLYBDENUM(VI) AND TRIPHENYLPHOSPHINE
    DURANT, R
    GARNER, CD
    HYDE, MR
    MABBS, FE
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (09): : 955 - 956
  • [6] MOLYBDENUM(VI) COMPLEXES AS OXIDANTS
    GARNER, CD
    DURANT, R
    MABBS, FE
    [J]. INORGANICA CHIMICA ACTA, 1977, 24 (02) : L29 - L30
  • [7] GOETZ H, 1967, LIEBIGS ANN CHEM, V704, P1
  • [8] GRINSHTEIN E, 1961, DOKL AKAD NAUK SSSR+, V139, P1359
  • [9] OXIDATION OF HYDRAZINE BY MOLYBDENUM(6)
    HUANG, T
    SPENCE, JT
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (12) : 4198 - &
  • [10] MOLYBDENUM(6)-CATALYZED OXIDATION OF HYDRAZINE BY METHYLENE BLUE
    HUANG, T
    SPENCE, JT
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (13) : 4573 - &