RATE CONSTANTS OF REACTION OF NITROGEN-ATOMS WITH 7 SIMPLE OLEFINS, 1,3-BUTADIENE AND ACETYLENE AT ROOM-TEMPERATURE

被引：13

作者：

SATO, S

SUGAWARA, K

ISHIKAWA, Y

机构：

[1] Department of Applied Physics, Tokyo Institute of Technology, 152, Ookayama, Meguro-ku, Tokyo, Japan

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(79)87260-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rate constants of reaction of nitrogen atoms with seven simple olefins, 1,3-butadiene and acetylene have been measured by the pulse-radiolysis technique combined with the measurement of absorption of the resonance lines of nitrogen atoms around 120.0 nm. The obtained values range from 0.2 to 2.0 × 10-13 cm3 molecule-1 s-1. These results are compared to previous studies. © 1979.

引用

收藏

页码：557 / 560

页数：4

相关论文

共 8 条

[1] RATES OF ENERGY TRANSFER FROM N2A3SIGMA+U TO VARIOUS MOLECULES - INITIAL AND FINAL QUANTUM STATES IN TRANSFER TO NOX2PI AND HG(61S0), AND VIBRATIONAL RELAXATION OF N2A3SIGMA+U(V=1) IN HELIUM [J].

CALLEAR, AB ;

WOOD, PM .

TRANSACTIONS OF THE FARADAY SOCIETY, 1971, 67 (578) :272-&

[2] ARRHENIUS PARAMETERS FOR REACTIONS OF ATOMIC NITROGEN WITH SOME OLEFINS AND ACETYLENES [J].

HERRON, JT ;

HUIE, RE .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (07) :2538-&

[3] MASS SPECTROMETRIC STUDY OF RATES OF REACTIONS OF NITROGEN ATOMS WITH OLEFINS [J].

HERRON, JT .

JOURNAL OF PHYSICAL CHEMISTRY, 1966, 70 (09) :2803-&

[4] ABSOLUTE RATE CONSTANTS OF REACTION OF HYDROGEN-ATOMS WITH SEVERAL OLEFINS [J].

ISHIKAWA, Y ;

YAMABE, M ;

NODA, A ;

SATO, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (09) :2488-2492

[5] G-VALUE OF NITROGEN-ATOMS PRODUCED IN GAMMA-RADIOLYSIS OF LIQUID-NITROGEN AND OZONE FORMATION IN GAMMA-IRRADIATED LIQUID-NITROGEN SOLUTION OF OXYGEN [J].

MATSUMOTO, A ;

YUGETA, R ;

KARASAWA, H ;

SATO, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (10) :2838-2840

[6] SELECTED RATE CONSTANTS FOR H, O, N, AND C1 ATOMS WITH SUBSTRATES AT ROOM TEMPERATURES [J].

MICHAEL, JV ;

LEE, JH .

CHEMICAL PHYSICS LETTERS, 1977, 51 (02) :303-306

[7] NON-EMPIRICAL CALCULATION OF G-VALUES FOR IONIZATION AND EXCITATIONS IN DIATOMIC-MOLECULES IRRADIATED BY 100 KEV ELECTRONS [J].

OKAZAKI, K ;

SATO, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1975, 48 (12) :3523-3528

[8] VACUUM-ULTRAVIOLET PHOTOLYSIS OF N2O .2. DEACTIVATION OF N2(A 3SIGMAU+) AND N2(B 3PIG) [J].

YOUNG, RA ;

BLACK, G ;

SLANGER, TG .

JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (01) :303-&