SYNTHESIS OF D-GLUCOSE 3-[2-(PERFLUOROALKYL)ETHYL PHOSPHATE] AND 6-[2-(PERFLUOROALKYL)ETHYL PHOSPHATE] - A NEW TYPE OF ANIONIC SURFACTANT FOR BIOMEDICAL USE

被引：15

作者：

MILIUS, A ^{[1
]}

GREINER, J ^{[1
]}

RIESS, JG ^{[1
]}

机构：

[1] UNIV NICE SOPHIA ANTIPOLIS,CHIM MOLEC LAB,CNRS,URA,PARC VALROSE,F-06108 NICE 02,FRANCE

来源：

CARBOHYDRATE RESEARCH | 1992年 / 229卷 / 02期

关键词：

D O I：

10.1016/S0008-6215(00)90578-0

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

D-Glucose 3- and 6-[sodium 2-(perfluoro-hexyl or -octyl)ethyl phosphates] have been synthezised by condensation of 1,2,3,4,-tetra-O-acetyl-beta-D-glucopyranose and 1,2:5,6-di-O-isopropylidene-alpha-D-glucofuranose with 2-(perfluoroalkyl)ethylphosphoroditriazolides followed by O-deacetylation or deacetalation. The structures of the compounds were established on the basis of H-1-, F-19-, P-31-, and C-13-NMR data. These salts display strong surface activities and appear to have good biocompatibility.

引用

页码：323 / 336

页数：14

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